Catoctin/Fauquier contact

Catoctin/Fauquier contact
Power washing a quarry block near Aldie, VA that preserves a soft sediment contact of the Fauquier Formation cap carbonate and pillow basalt of the Catoctin Formation.

Thursday, February 22, 2024

Impulsive Starts to inner sphere of Three Meter Experiment

Magnetic field measured from one of the external magnetometers when the inner sphere is spun up to its maximum rotation rate. Semi-log plot of this growth shows a linear behavior, indicating exponential growth.

We achieved significant magnetic activity in the redesigned system. One of the main examples of this is seen in the transient response of the field with an impulsive inner sphere start.


Exponential growth over one order of magnitude suggests dynamo growth with a time constant of 2.1 seconds. This exponential growth comes from the solution to the linear kinematic dynamo problem, for a particular eigenmode you get a set of complex eigenvalues, the real part is the growth rate. Exponential growth from the same runs in the past was insignificant and occurred over longer time scales.

This work is motivated by the successful dynamo obtained from the von Kármán Sodium experiment [1].

Bifurcation curves. (a) Measured azimuthal field growth with respect to magnetic Reynolds number (Rm). Rm is proportional to the rotational speed * radius of vessel. The solid lines correspond to a best fit with a scaling behavior above threshold. Impellers counter-rotating at equal rotation rates in the positive direction shown as closed blue circles or in the opposite direction, i.e., with the blades on the impellers moving in a scooping or negative direction (open red squares). 
(b) Measured Magnetic field Amplitude 
with respect to magnetic Reynolds number (Rm).
 

Oceanic Uranium Budget

 

Schematic representation of the modern U oceanic budget. The isotopic composition of each U reservoir can be read on the x-axis. For the sinks, the area of the boxes is proportional to the U flux out of the ocean (Tissot and Dauphas, 2015).

References:
Tissot, F.L.H., and Dauphas, N., 2015, Uranium isotopic compositions of the crust and ocean: Age corrections, U budget and global extent of modern anoxia: Geochimica et Cosmochimica Acta, v. 167, p. 113–143, doi:10.1016/j.gca.2015.06.034.

Metamorphic Ages Derived from Meteorites

 Meteorites are commonly dated using the 182Hf-182W decay (t1/2 = 8.9 Myr), a radiogenic process which is used to date the timing of core formation in terrestrial planets and other planetary bodies. Short-lived nuclides are optimal for dating processes that occurred within a relatively short time frame during the early Solar System because they can provide a high-resolution time scale for comparison (Holst et al., 2013). 

Calcium-Aluminum rich inclusions (CAIs) are the oldest known rock particles that condensed in our Solar System, and their remains can be found in primitive meteorites. Thus, a common method of dating chondrites is to analyze the difference in time since formation for bulk and/or metal separates and the CAIs found within the same sample.

The graph below records the Hf-W ages derived via bulk chondritic analyses from a suite of H and CR chondrites, and comparing the ε182-W of each separate to the ε182-W of the bulk chondrite and the initial ε182-W of CAIs. (Archer et al., 2019). 

Each shape represents a different chondrite which is named along the y-axis. The x-axis measures time since the last significant metamorphic event (in millions of years), which can also be considered time since CAI formation for meteorites which have remained relatively undisturbed since the early Solar System era. 

Section (a) houses the slope-derived ages for non-magnetic (NM) and slightly magnetic (SM) bulk separates. In section (b), the solid fills represent coarse metal grain separates (>150 um) and the shaded fills represent the finer grains (<150um). 

The error bars are the uncertainties for CAI ages calculated using the reported values from Kruijer et al. (2014). 

References

1. Archer G., Walker R., Tino J., Blackburn T., Kruijer T., Hellmann J. 2019. Siderophile element constraints on the thermal history of the H chondrite parent body. Geochimica et Cosmochimica Acta 245 pp 556-576

2. Holst J., Olsen M., Paton C., Nagashima K., Schiller M., Wieland D., Larsen K., Connelly J., Jorgensen J., Krot A., Nordlund A., Bizzarro M. 2013. 182Hf-182W age dating of a 26Al-poor inclusion and implications for the origin of short-lived radioisotopes in the early solar system. Proceedings of the National Academy of Sciences of the United States of America v110 n22 (20130528): pp 8819-8823

3. Kruijer T. S., Kleine T., Fischer-Go¨dde M., Burkhardt C., Wieler R. (2014) Nucleosynthetic W isotope anomalies and the Hf-W chronometry of Ca-Al-rich inclusions. Earth Planet. Sci. Lett. 403, 317–327.


REE Spider Plot

 

Figure 1:  Spider plot highlighting different PAAS-normalized
REE patterns representing natural environments and minerals that display the anomalous features of REE.  Seawater patterns are typically universal while other patterns (like pore waters) tend to vary on a local scale (Tostevin et al., 2016).



References:

Tostevin, R., Shields, G. A., Tarbuck, G. M., He, T., Clarkson, M. O., & Wood, R. A. (2016). Effective use of cerium anomalies as a redox proxy in carbonate-dominated marine settings. Chemical Geology, 438, 146–162. https://doi.org/10.1016/j.chemgeo.2016.06.027  











Thursday, February 15, 2024

Oddo-Harkins Effect: Why We Normalize REEs

 The foundations of the universe were created during the Big Bang event (13.7 GA), where an infinite amount of energy was condensed to a single point, then exploded outwards. About 98% of the universe's elemental abundance was formed within the first three minutes of this event in a process called Big Bang nucleosynthesis, and the remaining 2% was synthesized later by stars[5]. Nucleosynthesis is the process of creating new atomic nuclei by combining neutrons and protons (fusion) or breaking larger atomic structures apart (fission and radioactive decay)[3]. During stellar nucleosynthesis, fusion processes such as proton chains and the CNO cycle often result in the perpetual combination of even numbered elements (helium binds with continuous amounts of helium). The synthesis of odd numbered elements is less common, as it can only be done using leftover hydrogen elements or during supernovae[4]. This phenomena is referred to as the Oddo-Harkins effect which states that elements with an even atomic number are more abundant than their adjacent odd-numbered elements; for example, carbon (atomic number of 6) is more enriched than boron (atomic number of 5) and nitrogen (atomic number of 7).

Figure 1. A logarithmic elemental abundance chart displaying the "zig-zag" Oddo-Harkins effect. Image Credit: Wikipedia 

The overabundance of even elements creates a "distracting" zig-zag effect in elemental abundance graphs, making pattern recognition and direct comparisons between elements challenging. This is especially true in regards to the analysis of rare earth elements (REEs, a.k.a. the lanthanides) which are commonly used to constrain geological processes[2]. To resolve this dilemma, geochemical studies often normalize elemental abundance charts using CI chondrites to minimize the Oddo-Harkins effect. 

Chondrites are the primitive remains of cosmic sediments that did not accrete into planets. CI chondrites are a rare, stony type of meteorite that are rich in volatiles, but they are highly regarded for their unique chemical composition. The elemental ratios within CI chondrites are remarkably similar to that of the Sun in our  Solar System (see figure below). Thus, this link between CI abundance and the solar photosphere has been used as a geochemical standard to "cancel" or "normalize" the effects of stellar biases (e.g. the Oddo-Harkins effect). With the removal of "pre-solar system processes", elemental analyses are readily examined for the trends and behaviors which stem from later, secondary processes[1,2].

Figure 2. An elemental abundance chart displaying the 1:1 ratio between a CI chondrite (Orugueil) and the Solar Photosphere.

References

  1. Aleon, J. Meteorites and the physico-chemical conditions in the early solar nebula. Physics and Astrophysics of Planetary Systems, Les Houches. 2018. DOI:10.1051/eas/1041020
  2. Cornell, D. H. Rare earths from supernova to superconductor. Pure and Applied Chemistry. Vol 65, No. 12, 2453-2464. https://doi.org/10.1351/pac199365122453
  3. Helmenstine, A. Nucleosynthesis-How Elements Are Made. Science Notes. 2023. https://sciencenotes.org/nucleosynthesis-how-elements-are-made/
  4. Inglis-Arkell, E. The Oddo-Harkins Rule shows the universe hates the odd. Gizmodo. Published October 17, 2013. https://gizmodo.com/the-oddo-harkins-rule-shows-the-universe-hates-the-odd-1446581327
  5. Schramm, David, "The Big Bang Creation of the Universe", in Quarks, Quasars and Quandries, Ed. Gordon Aubrecht, Amer. Assoc of Physics Teachers, 1987.

Hitchhiker's guide to the Outer Core: The Induction Equation

This article is a second installment in my series on the Geodynamo and our Three Meter laboratory experiment that models it. To review, the earth's outer core is home to an important process which scientists refer to as the Geodynamo (Geo = Earth, dynamo = power; thus it describes how the magnetic field of our Earth is powered). This process is responsible for the generation of magnetic fields in the liquid metal of the outer core. 

We continue our story on the Geodynamo by looking at the important governing equation: the Induction Equation. As its name suggests, this mathematical model describes how the magnetic field is induced, or created, from the dynamics of the fluid flow. We quantitatively describe the flow of a fluid by its velocity field. For a typical laminar (or smooth) flow, it is fairly simple and predictable. However, as we increase the size and the velocity of our system, we have a more complex turbulent flow. 

Velocity field lines for laminar flow (left) and turbulent flow (right) for fluid through a cross-section of a pipe. Laminar flow lines are smooth, straight, and follow a straightforward pattern. The turbulent scenario is messier; there are swirls, or eddies, in the flow. Source: https://www.michael-smith-engineers.co.uk/resources/useful-info/pipe-velocity


The other major part of the induction of the magnetic field comes from the electromagnetic properties of the fluid. As such, we use Maxwell’s equations for changing electric and magnetic fields, and Ohm's law relating current density to the electric field:




Combining these equations, we can cancel out E and J and arrive at the Induction equation:



This is very similar to the equation for the vorticity (ω) of a fluid, or how much the fluid swirls, and is based on the curl of the conservation of momentum for a fluid:



This analogy to the vorticity equation is rather profound. The first term is a common diffusion term, showing that energy is lost by the magnetic diffusivity (η), which is associated with the electrical resistance of the material, like heat dissipating through friction. The second term is analogous to vortex stretching: imagine you are holding a string vertically on both ends, and in the middle a ball is attached. As you swing the ball around, you sweep a circle roughly parallel with the ground. But pull the two ends together and the ball gets faster. The general idea is reflected as vortices, or swirls in the fluid, naturally elongate, or stretch, as a property of turbulence. To not overcomplicate things, the general idea is that as these vortices stretch the preexisting magnetic field, thereby strengthening it. 


A rotating part of the fluid will tend to stretch out perpendicular to the plane of rotation resulting in smaller eddies spinning faster. This transition from energy held in large vortices to smaller vortices is due to the turbulent energy cascade. The top right of the video briefly shows this concept. Source: https://www.youtube.com/watch?v=_UoTTq651dE&pp=ygUONS8zIHR1cmJ1bGVuY2U%3D
 

The Induction equation is inherently complex and nonlinear due to this stretching term; a steady increase in the velocity of the fluid does not mean a steady increase in the magnetic field strength. This is because magnetic fields interact with the fluid’s electrical conductivity. As the fluid moves, it generates electric currents, altering the magnetic field. Just as vorticity amplifies due to fluid interactions, the magnetic field strength responds nonlinearly to fluid motion and electromagnetic effects.


On account of the equation's nonlinearity, solving it analytically is difficult. Computational simulations use advanced numerical methods and algorithms that break down the equation into manageable steps and approximate the solutions over small time intervals. Over the past 30 years, simulations based on the Induction equation have been successful in replicating a dynamo, but it is still unclear as to what the exact dynamics are, specifically on earth, that have allowed this magnetic amplification. 


A snapshot of the simulated geomagnetic field produced by Glatzmaier and Roberts (1995). The lines follow the paths of magnetic fields generated from fluid motions. This is taken during a supposed polar reversal.


The core reason numerical simulations cannot model earth's dynamics ultimately stems from the concept of energy cascades, via turbulence. Large eddies literally cascade into smaller eddies; you may notice this when you stir milk into coffee and watch what happens over time. To model both the large eddies in earth's outer core down to the teeniest of eddies on the micrometer size, you need extremely high resolution and computing power, that which even the best supercomputers cannot achieve.


Smoke and air mixing over time, illuminated by a green planar laser. Large eddies are visible but these all break down into smaller and smaller eddies. Source: https://www.youtube.com/watch?v=_UoTTq651dE&pp=ygUONS8zIHR1cmJ1bGVuY2U%3D




References


1. R. Beck, Magnetic fields in spiral galaxies, The Astronomy and Astrophysics Review, 24, 4 (2015)

2. Bondi, Hermann Sir and Thomas Gold. “On the Generation of Magnetism by Fluid Motion.” Monthly Notices of the Royal Astronomical Society 110 (1950): 607-611.

3. Glatzmaiers, G., Roberts, P. A three-dimensional self-consistent computer simulation of a geomagnetic field reversal. Nature 377, 203–209 (1995). https://doi.org/10.1038/377203a0



How do We Express Isotopic Ratios?

 







The typical equation for delta notation is shown in the red box, with a hypothetical example below.

Cerium anomaly calculation

Cerium is a unique rare earth element, that unlike its neighbors, can exist in both the +3 and +4 state.  Because of its unique behavior, cerium can be used to track oxygenation in the local water column insofar as in the presence of oxygen, Ce(III) is partially oxidized to Ce(IV) on the surface of Mn oxides, where it no longer participates in solid solution exchange reactions, depleting the residual seawater in Ce relative to the other REE (Tostevin et al., 2016).  This drives what is called a negative cerium anomaly, which is pervasive in the modern, well-oxygenated ocean. Under anoxic conditions, Ce remains in the Ce(III) state and is enriched in seawater relative to its neighboring rare earth elements.   

To calculate a cerium anomaly, one must first normalize (or divide) the measured concentration by a universally accepted reference concentration, which in this case is the post-Archean Australian shale (PAAS).  Once the elemental data has been normalized, the cerium anomaly is calculated using the following equation:


             

            Where [Ce] is the shale-normalized concentration of cerium, [Pr] is the shale-normalized concentration of praseodymium, and [Nd] is the shale-normalized concentration of neodymium.  There is an alternative equation that utilizes lanthanum to calculate the anomaly.  However, due to the anomalous behavior of lanthanum, the alternative equation may drive an artificial cerium anomaly.

Thursday, February 8, 2024

Journey Near the Center of the Earth: The Outer Core

Why do our compasses point north? Most people know it is because of our Earth's magnetic field, but how is it created? To answer this, I’d like to take you on a journey roughly 1,800 miles down to the outer core (like going from New York City to Denver). The outer core is home to an important process which scientists refer to as the Geodynamo. This process is responsible for the generation of magnetic fields in the earth's liquid layer, the outer core, which is made up of melted iron and nickel metal. Our Earth's magnetic field protects us and other animals from harmful solar radiation, and is therefore something we cannot live without! By studying the Geodynamo, we can get a better understanding of what happened in earth's past that allowed it to exist as well as what may happen to our field in the future.

A depiction of the Earth's magnetic protecting us from the solar rays. Credit: © ESA/ATG medialab.

To the right: the whispy white loops portray the magnetic field around the Earth, seen here as partially transparent. The outer core is highlighted in fiery red, and the black ball in the center is the inner core. The magnetic field lines gather at the North and South poles of our earth, and this is why we have the Northern and Southern Lights!


The exact mechanisms that occur to bring about this dynamo are not well known, for obvious reasons: inaccessibility to earth’s deep interior, and the complexity and chaotic behavior of magnetic field measurements. We know that the solid metal inner core is almost as hot as the surface of the Sun, so it cannot be the cause of the magnetism. This, along with the discovery of the liquid metal outer core, gave rise to the Geodynamo theory.


Scientists in the 40s and 50s were able to produce a mathematical (or analytical) model for how the Earth's field changes over time. This model, which we refer to as the Induction equation, essentially shows how the fluid stretches and twists the magnetic fields and thereby amplifies them, like water in a tornado. So how the fluid flows has immense implications for whether or not the total magnetic field will grow or decay. But the Induction Equation cannot be solved on paper to determine what type of fluid flows or magnetic fields produce the type of magnetic fields we measure on Earth.


A tornado stretching and twisting the air around it. It is visible due to the water and dust that it sucks up with it. Source: BBC America. This twisting tube is called a vortex (plural: vortices), and is an important feature in fluid flows. When the fluid is a good electrical conductor or metallic, the vortices can twist and stretch the magnetic field lines!


Although computational simulations have been successful in replicating a dynamo, it cannot reproduce the exact dynamics on Earth because of the limited range of scales that computers can capture: in the outer core, the features of the fluid flow can range from hundreds of miles all the way down to the tiny molecular level! 

To truly understand and better replicate the outer core's characteristics, we need a physical model, or a laboratory analogue. At the University of Maryland, one such experiment exists: the Three Meter.


A peek into our experiment: our former grad student stands on top of the experiment's house: a metal box. Directly below him sits the Three Meter. You are looking at the exterior, which looks like it has a tube wrapped around it. This tube is filled with hot oil that keeps the sodium inside melted!
 

As its name suggests, the experiment is 3 meters (or roughly 3 yards) large and inside has a shell that is filled with liquid metal. In our case this metal is not iron, but sodium, as it melts at regular cooking temperatures, is lightweight, and a very good conductor (the Geodynamo needs a good electrical conductor to work). We can spin the shell to bring on fluid flow in ways that may occur in the outer core, due to the spin of Earth and the natural circulation in the outer core. By taking magnetic measurements of the experiment while it is spinning, we can determine what sorts of conditions are required for there to be a growth in the magnetic field. We may be able to translate this into the conditions that Earth was under to achieve a growth in the magnetic field.

An enigmatic origin for early animal biomineralization?

What is biomineralization and why is it important?

 

A modern example of animal biomineralization is shown by
this conch shell. Mollusks use their shells to defend against
larger animals that may want a tasty snack as well as regulating
their internal chemistry (eBay).  
   Biomineralization is the process by which living organisms produce minerals, often resulting in hardened or stiffened tissues.  Animals biomineralize to create bones, teeth, and shells to provide structural support, protection from consumption, and maintain a healthy chemical balance (think about snails and their shells for example).  
However, when animals first acquired the ability to biomineralize remains shrouded in mystery.  Discoveries of an early worm-like animal with a carbonate shell, called Cloudina, in southern Namibia, led to a prediction that these organisms would be found in equivalent rock successions across the world.  A field excursion based on this prediction led to Siberia, where Cloudina were not found, but a groundbreaking discovery was made.  In a fossilized reef complex of an ancient rock formation, strange sponge-like fossils with biomineralized calcium carbonate shells were discovered.  This was a major discovery as these fossils may represent the oldest examples of sponge-like animals at approximately 600 million years old!




Top: Cloudina microfossils that were extracted from a
 microbial reefal core found in the Villarta Formation in
Spain (Alvaro et al., 2019)
Bottom:  Outcrop photo of the sponge-like bioclasts in the 
Siberian Chencha Formation reef complex (Kaufman, 2021)
So why is this important?

     Despite the significant geographical distance between these two formations, they, amongst several other formations elsewhere on the planet, host unique geochemical signatures that have left researchers perplexed for years due to the data signifying an ocean with very different chemistry than in the modern ocean.  One element that researchers use to assess ocean chemistry is carbon.  Aside from being the building block of all life forms, researchers use carbon to reconstruct shifts in the composition of seawater throughout Earth history, correlate between rock units locally and globally, and construct age models. 

 

So how does this relate back to the discovery of the organisms?

 

    The formations in which these biomineralizing organisms were found, host one of the greatest negative carbon cycle anomalies in Earth history, known as the Shuram Excursion, named after the rock formation in Oman where it was discovered.  The absence of a reliable age date for the duration of the event, the magnitude of the anomaly, the uncertainty surrounding the onset of the event, and potential for alteration in such ancient rocks makes this a controversial topic.  Recent geochemical data has been used to constrain the chemical composition of the oceans roughly 600 million years ago to better understand the conditions in which early animals may have acquired the capability to biomineralize.  Elemental data reveals enhanced weathering of the continents during this time period, likely due to large-scale tectonic rearrangement, which would have delivered nutrients, calcium ions, and sulfate to the oceans, stimulating microbial processes that would consume organic matter and sulfate to produce carbonate that would bind with the calcium ions to precipitate calcium carbonate.  The appearance of the biomineralized fossils towards the end of the Shuram suggests that the calcium levels were so high that the animals could not expel the excess calcium from their bodies at a fast enough rate so they had to get creative, and thus they started producing shells.  Building upon the weathering data, additional elemental data suggests that the oceans prior to 600 million years ago contained very little oxygen, or were anoxic, while during and after the profound change in ocean chemistry, the oceans may have reached near modern oxygen levels.  This may have been attributed to the actions of the sponge-like fossils which, during life, would have filtered massive amounts of water, clarifying the surface oceans, allowing for photosynthesizing organisms to ventilate the oceans.

 






Orientation of the continents approximately 565 million years ago which is tremendously different than the modern orientation.  The names of the continents are very different than the modern names:
Am, Amazonia; Ar, Arequipa; Aus, Australia; Az, Azania; Ba, Baltica; C, Congo; I, India;
K, Kalahari; Lau, Laurentia; SC, South China; Si, Siberia; T, Tarim; WAC, West African Craton
Each symbol represents known Shuram Excursion intervals (modified from Busch et al., 2022).

For more information please refer to:

Álvaro, J. J., Cortijo, I., Jensen, S., Martí Mus, M., & Palacios, T. (2020). Cloudina-microbial reef resilience to substrate instability in a Cadomian retro-arc basin of the Iberian Peninsula. Precambrian Research336, 105479. https://doi.org/10.1016/j.precamres.2019.105479

Busch, J. F., Hodgin, E. B., Ahm, A.-S. C., Husson, J. M., Macdonald, F. A., Bergmann, K. D., Higgins, J. A., & Strauss, J. V. (2022). Global and local drivers of the Ediacaran Shuram Carbon Isotope Excursion. Earth and Planetary Science Letters, 579, 117368. https://doi.org/10.1016/j.epsl.2022.117368

Cui, H., Kaufman, A. J., Xiao, S., Zhou, C., & Liu, X.-M. (2017). Was the ediacaran shuram excursion a globally synchronized early diagenetic event? insights from methane-derived authigenic carbonates in the uppermost Doushantuo Formation, South China. Chemical Geology450, 59–80. https://doi.org/10.1016/j.chemgeo.2016.12.010 

Li, Z., Cao, M., Loyd, S., Algeo, T., Wang, X., & Zhao, L. (2020). Transient and stepwise ocean oxygenation during the Ediacaran Shuram Excursion. Goldschmidt Abstractshttps://doi.org/10.46427/gold2020.1541

Rothman, D. H., Hayes, J. M., & Summons, R. E. (2003). Dynamics of the Neoproterozoic carbon cycle. Proceedings of the National Academy of Sciences100(14), 8124–8129. https://doi.org/10.1073/pnas.0832439100


    • Rachel A. Wood et al.
    •  
    ,
    Proterozoic Modular Biomineralized Metazoan from the Nama Group, Namibia.Science296,2383-2386(2002).DOI:10.1126/science.1071599 

    Uriz, M.-J. (2006). Mineral skeletogenesis in sponges. Canadian Journal of Zoology84(2), 322–356. https://doi.org/10.1139/z06-032  

    The mysterious disappearance of the Ediacaran organisms

    What were the Ediacaran organisms? 


    Almost six hundred million years before humans walked the Earth, the ocean floor was dominated by some of the earliest experiments in animals, known as the “Ediacaran biota”. They roamed the ocean floor during the Ediacaran Period up until the beginning of the Cambrian Period, from ~600 million years ago to 538.8 million years ago. These creatures represent a diverse array of species, without any resemblance to life that we see today. The wide variety of forms range from simple disc-shaped organisms (Dickinsonia and Kimberella) to more intricate frond-like structures (Charnia). They are generally characterized by their soft bodies and lack of hard parts (such as shells or skeletons), making it difficult to preserve complete specimens in the rock record. Today, these animals are often found in the form of impressions or molds in fine-grained sedimentary rocks, which allows us to study them in great detail. While their forms were relatively simple, their bodies contain detailed symmetrical patterns, which may have benefitted them in life. It is still a mystery as to what kind of lifestyle these organisms maintained, but current research suggests that they could have been filter feeders, photosynthesizes, or possibly engaged in symbiotic relationships.


    Illustration of the Ediacaran organisms (above) and fossils (below) (Art by Peter Trusler). 

    What happened to the Ediacaran organisms?

    The transition between the Ediacaran and Cambrian periods is marked by the sudden disappearance of the Ediacaran biota. It is still unknown just what exactly caused the extinction of these creatures. Current hypotheses point towards environmental as well as biological causes. Clues about their lifestyle (and death) may be found by studying the rocks in which the animals are found. Carbonate rocks that contain fossils of Ediacaran organisms have been studied to reconstruct the amount of oxygen present during the time that they lived. A recent study that did this has found that the Ediacarans may have survived under low oxygen conditions. If they maintained a lifestyle that did not require much oxygen, then it is possible that an increase of oxygen could be responsible for their death. Consistent with this idea, carbonate rocks during this time record a disturbance in the carbon cycle. However, recent work reconstructing the oxidation state during this transition has found there to be no change in the oxygen level, leading the door open for other mechanisms to cause the extinction of the Ediacaran biota.

    In some locations the disturbance in the carbon cycle is interpreted as the falling of sea level. Additionally, higher rates of evaporation are supported by higher oxygen isotope values during this time. Sea level drop may have had negative impacts on these organisms. As the Ediacaran biota were simple creatures, their bodies were made up mostly of water, so the falling sea level could increase the salt concentration of the oceans. This would cause the fresher water contained within their bodies to diffuse out of them, essentially dehydrating and killing them. 

    Alternatively, studies have been done that point towards biological changes that may have resulted in the extinction of the Ediacaran animals. As the Ediacaran Period came to an end, and the Cambrian Period was beginning, new forms of life began to emerge. These new creatures may have engineered the ecosystem to better suit themselves. By burrowing into the ground, the new Cambrian animals disturbed the algal mats that the Ediacarans fed on, eliminating their primary food source. The inability to compete with bioturbation associated with new Cambrian organisms may have led to the extinction of the Ediacaran biota.

    Illustration of the transition from the Ediacaran (left) to the Cambrian (right) Ediacaran ecosystems existed at or near the surface, while Cambrian ecosystems extended deeper into the ground. (Art by Peter Trusler). 


    It is possible that environmental changes, biologic changes, or a combination of both caused the extinction of the Ediacaran organisms. Scientists around the world are working to answer this question, but without a time machine it is impossible to know with complete certainty what caused these mysterious creatures to suddenly disappear. Despite these animals bearing little to no resemblance to modern organisms, understanding how they went extinct may help us better understand how the creatures of today may go extinct as well. 


    Wednesday, February 7, 2024

    (Not so) Ordinary Chondrites!: A Glance into the Early Solar System

    Have you ever looked into the night sky, and caught the faint glimmer of a streak? Have you seen a movie where a giant, mysterious stone with a glowing hue crashes into the ground? Those are meteors, gifts from the great beyond! Meteors and meteorites are extraterrestrial rocks that formed from cosmic dust in outer space, then fall to Earth's surface. Although in reality, they don't usually carry aliens or grant superpowers, meteorites (or chondrites as scientists call them) can be used to study many dynamic and spectacular phenomena that occurred billions of years ago in the early Solar System.

    Ordinary Chondrites (OCs) are the most common type of meteorite falling to Earth's surface today (about 80% [2]). Their main ingredients are silicate (rock) and metal grains. OCs are special because they are made of material from the solar nebula that formed the Solar System, and have remained relatively unchanged since they formed. The only major process OCs experience is "thermal metamorphism" which is when heat bakes the ingredients inside. The primitive nature of OCs make them great subjects to study early Solar System processes. They have even been used to gain insight into the mechanics of core and planetary formation [1]!

    OCs contain different amounts of metallic iron - so they can be very shiny and a polished surface would glimmer in the light! There are three major categories; H, L, and LL [3]. H chondrites contain the most amount of metallic iron (15-20% by mass). Fun fact: the "H" stands for "high" iron! Geologists aren't always the best at coming up with cool names... L chondrites have low amounts of metallic iron (7-11% by mass). As you might have guessed-- the "L" stands for "low"! Finally, we have LL chondrites which have even lower amounts of metal (3-5% by mass).

    You might remember that I mentioned OCs can experience thermal metamorphism (or baking). Well, scientists have ways to tell how much heat an OC has gone through! There are different levels of heat activity which are known as "metamorphic types". The temperature increases as you go from type 1 to 6. My research involves analyzing the metal grains in OCs to learn about how they are baked and changed by heat. This will help us to understand core formation (which involves a lot of thermal activity) because we will have a better idea of how metal changes when you crank the heat!

    Ordinary chondrites are beautiful relics of the early Solar System which grant us an opportunity to gaze into the past, and learn more about planetary origins. To stay updated on new OC falls or to see more interesting meteorites, check out the Meteoritical Bulletin. Watch the skies--the next OC may fall in your neighborhood!



    References

    [1]. Bottke, W.F., DeMeo, F.E., & Michel, P. (2015). Asteroids IV. Tucson: University of Arizona Press., https://doi.org/10.1353/book.43354.

    [2]. Britt, D. T. (1996). The Parent Asteroids of Ordinary Chondrite Meteorites. Lunar and Planetary Science, Volume 27, 167.

    [3]. Korotev, R. Metal, Iron, & Nickel in Meteorites. meteorites.wustl.edu. Washington University in St. Louis. July 2019


    Thursday, February 1, 2024

    (Not So) Ordinary Chondrites: A Glance into the Early Solar System

     Have you ever looked into the night sky, and caught the faint glimmer of a streak? Have you seen a movie where a giant, mysterious stone with a glowing hue crashes into the ground? Those are meteors, gifts from the great beyond! Meteors and meteorites are extraterrestrial rocks that formed from cosmic sediments in outer space, then fall to Earth's surface. Although in reality, they don't usually carry aliens or grant superpowers, meteorites can be used to study many dynamic and spectacular phenomena that occurred billions of years ago in the early Solar System.

    Ordinary Chondrites (OCs) are the most abundant meteorites falling to earth's surface today (about 80% of falls [2]). Their major components are silicates and metal grains. OCs are special because they are made of precursor material from the solar nebula that formed the Solar System, and they are relatively unprocessed aside from varying degrees of thermal metamorphism. This primitive nature makes them great subjects to study early Solar System processes, and they have even been used to gain insight into the mechanics of core formation and planetary differentiation [1].

    Thanks to the many samples that fall to Earth each year, scientists have designed a classification scheme to make OCs easier to study. There are three major categories; H, L, and LL [3]. H chondrites contain the most amount of iron (Fe) and tend to contain more metal (15-20% by mass). Fun fact: the "H" stands for "high" iron! Geologists aren't always the best at coming up with cool names... L chondrites are low in total iron and have less metal (7-11% by mass). And yes, you've guessed it-- the "L" stands for "low"! Finally, we have LL chondrites which are even lower in total iron and metal (3-5% by mass). In recent years, a new category named HH has emerged, and as you might guess, these samples are absolutely brimming with metallic iron [4]! However, they are quite rare, so keep your eyes peeled!

    Ordinary chondrites are beautiful relics of the early Solar System which grant us an opportunity to gaze into the past, and learn more about planetary origins. To stay updated on new OC falls or to see more interesting meteorites, check out the Meteoritical Bulletin. Be sure to watch the skies--the next OC may fall in your neighborhood!


    References

    [1]. Bottke, W.F., DeMeo, F.E., & Michel, P. (2015). Asteroids IV. Tucson: University of Arizona Press., https://doi.org/10.1353/book.43354.

    [2]. Britt, D. T. (1996). The Parent Asteroids of Ordinary Chondrite Meteorites. Lunar and Planetary Science, Volume 27, 167.

    [3]. Korotev, R. Metal, Iron, & Nickel in Meteorites. meteorites.wustl.edu. Washington University in St. Louis. July 2019

    [4]. Troiano, J., Rumble, D., Ricers, M., Friedrich, J. (2011) Compositions of three low FeO ordinary chondrites: Indication of a common origin with the H chondrites. Geochimica et Cosmochimica Acta Volume 75, Issue 21, 1 November 2011, Pages 6511-6519